Organic Chemistry
Baeyer–Villiger & Diels–Alder
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Peracid migration rules, stereospecificity, endo/exo selectivity, electron-demand criteria and reagent cluster mapping.
What you will be able to do
- Place the new oxygen in any Baeyer–Villiger product in seconds using the migration order
- Draw the Criegee mechanism and the concerted Diels–Alder with correct arrows
- Predict cis/trans, endo/exo and ortho/para outcomes of Diels–Alder reactions
- Group reagents like mCPBA and maleic anhydride by function across chapters
Inside these notes
- Baeyer–Villiger: the reaction
- The Criegee mechanism
- Peracid migration rules
- Diels–Alder: the [4+2] cycloaddition
- Stereospecificity and endo/exo
- Electron demand and regiochemistry
- Reagent cluster mapping
- Traps, MCQs and revision
Useful for: JEE Advanced · MHT CET · TGT/PGT · GATE · B.Sc.
The notes
